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| 구리 촉매 담지 대나무 활성탄의 NO 가스 반응 특성 |
| 박영철, 최주홍 |
| 경상대학교 화학공학과･공학연구원 |
| Kinetics of NO Reduction with Copper Containing Bamboo Activated Carbon |
| Young-Cheol Bak, Joo-Hong Choi |
| Department of Chemical Engineering･Engineering Research Institute, Gyeongsang National University |
| Corresponding author |
Young-Cheol Bak ,Tel: 055-772-1786, Fax: 055-772-1789, Email: ycbak@gsnu.ac.kr
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Received: April 6, 2015; Revised: September 9, 2015; Accepted: March 14, 2016. Published online: March 31, 2016. |
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| ABSTRACT |
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The metal-impregnated activated carbon was produced from bamboo activated carbon by soaking method of metal nitrate solution. The carbonization and activation of raw material was conducted at 900℃. The specific surface area and pore size distribution of the prepared activated carbons were measured. Also, NO and activated carbon reaction were conducted in a thermogravimetric analyzer in order to use as de-NOx agents of used activated carbon. Carbon-NO reactions were carried out with respect to reaction temperature (20℃~850℃) and NO gas partial pressure (0.1 kPa~1.8 kPa). As results, the specific volume and surface area of bamboo activated carbon impregnated with copper were decreased with increasing Cu amounts of activated carbon. In NO reaction, the reaction rate of Cu impregnated bamboo activated carbon[BA(Cu)] was promoted to compare with that of bamboo activated carbon[BA]. But the reaction rate of Ag impregnated bamboo activated carbon[BA(Ag)] was retarded. Measured reaction orders of NO concentration and activation energy were 0.63[BA], 0.92[BA(Cu)], and 80.5 kJ/mol[BA], 48.5 kJ/mol[BA(Cu)], 66.4 kJ/mol[BA(Ag)], respectively. |
| Key Words:
Activated Carbon, Bamboo Activated Carbon, Copper Impregnated, Silver, TGA, NO |
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